![]() Also down low, Bam Adebayo and Deandre Ayton mirror each other as athletic big men with high ceilings. Along the wing, each team has a cold-blooded, three level scorer in Devin Booker and Jimmy Butler. Handling the rock, both the Suns and Heat carry veteran, savvy point guards in Chris Paul and Kyle Lowry. Even with Miami missing a few stars, they still eerily resemble Phoenix at their core as an Eastern Conference counterpart and deserve considerable attention as another title-contending team. Cleveland Cavaliers vs.The Phoenix Suns hit the hardwood tonight facing off against the Miami Heat for the first time this season. Everyone else can look to NBA League Pass. Cleveland fans can watch on Bally Sports Ohio, while those in South Florida can watch on Bally Sports Sun. The “LeBron’s exes” showdown will be on local sports networks. HEAT (+9.5), UNDER What channel is the Cleveland Cavaliers game on? If the Cavs have separation late, look for them to cruise if it gets close, the Heat could surprise. The glaring red flag here is how the Cavs look closing out the game, their big weakness of the season thus far. That being said, the Cavs have their core four back and healthy, and the new-look starting lineup with Stevens looked good in its first appearance on Wednesday. The Heat are well-coached, their players fit the system and they shouldn’t be overlooked. If Adebayo is out there he will be the deadliest weapon at the center of the Heat’s zone-heavy defense, but there are enough other holes that the Cavaliers’ guards should be able to find space. Garland in particular is on a tear, with outings of 41 and 51 in his last three games. On offense, the Cavs will lean on Donovan Mitchell and Darius Garland, who look to be figuring out to be great together. If Adebayo does play, he will have a tough time orchestrating the offense with Evan Mobley and Jarrett Allen smothering him. Jimmy Butler is the isolation engine that makes this team go, with Tyler Herro as his undersized understudy with both out, the burden is put on an aging Kyle Lowry and Bam Adebayo. ![]() That should work against a Miami Heat team with will lack its best creators on Sunday. To win while the two are out, the Cavs likely shift into more of a defensive, grind-it-out style. Their absence means more minutes to players like Lamar Stevens, Isaac Okoro and Robin Lopez, none of whom are plus shooters. The Cleveland Cavaliers are going to miss Kevin Love and Dean Wade, especially on the offensive end as floor-spacers. Opponent: Kyle Lowry, Max Strus, Haywood Highsmith, Caleb Martin, Bam Adebayo Prediction Kevin Love (doubtful, thumb) Dean Wade (out, knee) Ricky Rubio (out indefinitely, knee) Dylan Windler (out indefinitely, ankle) Cleveland Cavaliers starting lineup tonightĬavs: Darius Garland, Donovan Mitchell, Lamar Stevens, Evan Mobley, Jarrett Allen With Jimmy Butler, Tyler Herro and multiple rotation players out, and Bam Adebayo questionable, the Cavs are a commanding 9.5-point favorites at home. As it is, the Cavs will be without multiple key bench players, but the Miami Heat will be down much more. Betting odds, spread, over/underĪt full strength, it’s hard to know which of these two teams Vegas would favor. The Heat were a shot away from the NBA Finals last season but have had a tough start to the year, sitting at 7-9 the Cavs have had an up-and-down year but overall look like a strong team, with a 9-6 record after surviving against the Charlotte Hornets on Wednesday. Now James is on the Los Angeles Lakers, but his legacy lives on in some part with the Cavs and the Heat, who meet on Sunday. In 2014 he returned home, spurning the Heat to join the Cavs once again, winning the title in 2016. ![]() ![]() In 2010, LeBron James infamously announced that he was taking his talents to South Beach, leaving the Cleveland Cavaliers to join the Miami Heat he would win two titles there. ![]()
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![]() ![]() Yes, your Fusion 12 Pro key will unlock Workstation 16 Pro on Windows or Linux. Fusion 12 Pro now supports individual use on up to 3 devices which now include Windows or Linux PCs running Workstation Pro. On top of this, there is also a new pricing model for Fusion PRO. So if you’re a home user who switched to Mac but want to use Windows for things like DX11 games or other personal apps, you can do so, for free, with a Personal Use License. Fusion Player has the same features as Fusion 11.5.x ‘standard’ and more. ![]() Fusion 12 Player replaces Fusion 11.5 ‘standard’, and follows the same pricing and licensing model as Workstation Player, meaning that it is both free for Personal Use, but requires a license for Commercial Use. VMware has decided to change the licensing model for Fusion and it is like this:įusion 12 Player (free for personal use license) and Fusion 12 PRO. So what's all the noise about here? Well, the biggest change apart from support for the upcoming BigSur macOS and several more features is the fact that for the first time Fusion is FREE! I will focus on the macOS side of the story here. Parallels 16 was released a few days ago and today we got a new version from a leading virtualization company VMWare.Īlong side Fusion (virtualization platform for macOS), we also got Workstation 12, version for Windows. With each year VMWare and Parallels release new versions of their virtualization platforms. Considering that my connection is so slow this will take some time for all 68GB to download. Upgraded my Win10 LTSC VM from compatibility level 16 to the latest 18 and started to install Doom (2016). UPDATE: (23:15 CEST) - Upgrade from 11.5 to v12 was fine with zero problems. On the other hand, Fusion runs just fine with no problems at all. The game detects the GPU as integraded card and it will not run, so no joy. ![]() ![]() ![]() It asks for critical information such as household income, monthly bill amounts and your social security number.Īfter submission, students must fax, email or mail in documents that support all information answered throughout the application. To apply, the process will involve setting up an account on the DCFS CAFE Self Service Portal and filling out an application, which can take up to 20 minutes your progress can be stopped and saved to return later on to finish at any point. The 20 hours per week requirement still applies if you are working a non-work-study job. This is the most important difference for SNAP for college students – if you are a work-study student, you must be working in a work-study job to qualify rather than needing to work 20 hours a week. Participate in a state or federally financed work-study program during the regular school year.Employed for an average of at least 20 hours per week and paid for such employment, or if self-employed, employed for an average of at least 20 hours per week and receive weekly earnings at least equal to the federal minimum hourly wage multiplied by 20 hours.Students can apply for assistance formerly known as food stamps online at the Department of Children and Family Services website and even check to see what other programs for which they are eligible.Īccording to the DCFS website, in order to be considered for SNAP you must b e enrolled at least half-time in an institution of higher education and meet at least one of the requirements: Once the funds are transferred to the card, the student can pay for their groceries at their nearest grocery store that accepts EBT such as Walmart, Rouses Market and many more. The supplemental allotments are loaded onto cards for electronic benefits transfer monthly and ready for use. SNAP provides monthly benefits to help low-income households buy the food they need for good health. Some of these programs, such as SNAP, have different requirements for college students than for members of the general public. Louisiana has always had assistance programs such as the Family Independence Temporary Assistance Program, Temporary Assistance for Needy Families and the Supplemental Nutrition Assistance Program. Many students have had cutbacks on job hours due to the pandemic and were taken out of their homes due to the last storm, Hurricane Ida, making it hard to stay afloat. Over the past two years, Louisiana students have endured not only COVID-19 but several hurricanes as well. ![]() ![]() Every year there is at least one Doug Martin-type who goes high in drafts and doesn't return value. He has played at least 15 games in six of seven seasons, so he is the least likely running back of the top options to fall off the cliff. Adding Ben Grubbs to the offensive line should help, and the additions of Jeremy Maclin and a fully healthy Travis Kelce to start the season will improve an offense that averaged five points per game fewer in 2014 than it did in 2013.īut the argument for Charles is found not in last year's stats but rather throughout his career. ![]() Touchdowns from year to year are fluky (and again, he scored nine rushing touchdowns), and he touched the ball almost 250 times. He averaged basically the same number of rushing yards after contact and receiving yards after contact and, per our friends at Pro Football Focus, actually had more fantasy points on a per-carry basis than he did in 2013.Ĭharles' touches were down last season, as were his touchdowns, so the people who want to knock him use those stats. Yes, he went from 19 touchdowns in 2013 to 14 last season, but look closer: He had the same yards per carry, and he was still top-five in the NFL among running backs in yards per rush, rushing touchdowns, receiving touchdowns and routes run. People will point to last season as being a down year for Charles, but I disagree. In fact, he is second in fantasy points during the past three years across all positions. Since Andy Reid took over the Kansas City Chiefs, no running back has scored more fantasy points in ESPN standard scoring than Charles. No, Jamaal Charles is as safe as they come. No suspensions looming, no insane usage during the past four years where you worry about a decline, no injury concerns, no age or off-the-field issues, no concerns about lack of carries or him being touchdown-dependent. (Truthfully, he's neck-and-neck with Peterson for me now that Peterson has reported to the Vikings, but this article is about Charles.) Charles is the safest guy. That safety is why Jamaal Charles is my pick for No. 1 pick." Both statements are practical, preaching being conservative over swinging for the fences early on. The other line I use a lot - I'm both a slave to tradition and fairly lazy - is this: "You don't have to finish the year as the No. ![]() Just ask anyone with Adrian Peterson on their team last year. If you blow your first-round pick, you're probably done for the season. The first round (especially the first pick) is not a place to get cute or mess around. "You can't win your league in the first round, but you can lose it." I've used that line a lot over the years, and it's proved to be true time and again. You have reached a degraded version of because you're using an unsupported version of Internet Explorer.įor a complete experience, please upgrade or use a supported browser ![]() ![]() Bright triplet excitons in caesium lead halide perovskites. c TRFE signal for two circular polarizations of pump: σ + (red) and σ − (blue). Metal halide perovskites (MHPs) with general formula of ABX 3. Bright Triplet Excitons in Caesium Lead Halide. Arrow at delay of − T D = −1.32 ns marks the position of the amplitude relaxation measurement. PDF The recent emergence of metal halide perovskites as triplet sensitizers has generated new possibilities in optoelectronics. Inset shows TRFE for negative time delays in the two-pump protocol. Exponential fit gives decay time of the burst amplitude τ = 0.5 s, corresponding to the changeover time between the distributions, after blocking the second pump. b Relaxation dynamics of the burst amplitude A FE(− T D) measured by switching from two-pump to one-pump protocol. Note, that the stronger hole-nuclear interaction compared to the electron-nuclear one is specific for lead halide perovskite semiconductors 35, due to their “inverted” band structure in comparison to semiconductors like GaAs or CdTe.Ī Schematic representation of the distribution ∣ S z ∣ of spin precession modes within the g-factor spread (green Gaussian) in the two-pump compared to the one-pump protocol. From its value and the strong changes of ω L in presence of polarized nuclei we conclude that the signal is dominated by resident holes with g h = +1.20 (see Supplementary Notes 1 and 2). 2c, see details below) indicate that the g-factor has a positive sign. General theoretical arguments and the experiments on dynamic nuclear polarization (Fig. Abstract: The lowest-energy exciton state in caesium lead halide perovskite nanocrystals is shown to be a bright triplet state, contrary to expectations that lowest-energy excitons should always be dark. Lead halide perovskites have emerged as promising new semiconductor materials for high-efficiency photovoltaics. In the latter case, an offset equal to the electron–hole exchange would be expected. In addition to this, lead-halide perovskite nanocrystals remain bright emitters when the size of the nanocrystal imposes only weak quantum confinement. S4a), which is a strong argument in favor of the presence of resident carriers in the NCs rather than of carriers bound in an exciton 23. ω L has no offset at zero magnetic field (Fig. This allows us to evaluate the g-factor of ∣ g ∣ = 1.20. The spin physics of perovskite nanocrystals with confined electrons or holes is attracting increasing attention, both for fundamental studies and spintronic applications. ![]() ![]() ![]() Welcome screen (click on the screenshots to enlarge it):Īs you can see, in the Maintenance tab you can update virus signatures and the software, register it, and access the Virus Chest (usually called Quarantine in antivirus software – the place where found malware is removed to).īefore starting anything, let’s check the general setting first. When it starts, you are immediately asked to register it, and you should if you want to use it beyond the 30-days trial period and to receive virus database updates. After an initial quick scan of the system, the process is complete and you can start the program. You are also offered to install Google’s Chrome browser, but you can decline if you don’t want to. The installation process is a breeze, and you can choose a custom installation if you want. It also incorporates anti-rootkit and strong self-protection capabilities, and contains several real-time “Shields” which continuously monitor your email and internet connections and check the files on your computer whenever they are opened or closed. It is highly recommended to try the official Avast tool first before you make use of third party software.Avast! Free Antivirus (v.5.1.864) is an anti-virus, anti-spyware software with boot-time scanning capabilities. The program can be useful if you need to remove supported Avast software from a Windows system and can't or do not want to use the official uninstaller to do so. Please note that the cleanup tool is only compatible with Windows Vista or newer versions of Windows, and not Windows XP. Once you click on accept, you will notice that two command line prompts are launched that perform the uninstallation of Avast software on the system. First screen displays information about the program and its intended uses. To completely uninstall a supported version of Avast, simply run the tool after you have downloaded it to your system. You should not use the program if you are running a different Avast product or version of a supported product. ![]() Avast! Antivirus 8.x Free/Professional/Internet Security/Premier.Avast! Antivirus 7.x Free/Professional/Internet Security.At the time of writing, it is supporting the following versions: It may also be your only hope if the official program for one reason or the other does not work properly.įirst thing you need to make sure is that it is supporting the version of Avast! that you have installed on your system. ![]() Why you'd use a third party program when there is a first party program available for the same task? Because you do not have to run it in safe mode which you need to do when you use the official Avast utility. The Avast! Cleanup Tool is a third party program that is not to be confused with the company's official removal program Avast! Uninstall Tool. Sometimes, they combine the list with searches to make sure that all program files and Registry information are removed from a computer system. These tools use hard coded lists of files and locations usually and are considered thorough because of it. The majority of companies that produce security software for Windows make available removal tools that delete all traces of a product from a system. ![]() ![]() ![]() Which version of Bluestacks do I need if I have a 32-bit Windows PC.Clean and malware free BlueStacks System Requirements Anti Cheat Engine Better performance on the integrated graphics card FAQs Make sure you know the actual facts about BlueStacks. Unfortunately, most of them are wrong, or even worst. There is a lot of rumor and misconception about BlueStacks. To enjoy a seamless gaming experience, BlueStacks lets you play your favorite Android Shooting games on PC by enabling High Frames Per Second so that you can react immediately in heavy combat. You can perform many actions with just one key or bind a single action to a single key. With this incredible feature, you can create and run a ‘Script’ to automate a series of repetitive actions. With BlueStacks, you can create multiple instances to reroll more time from each. Rerolling is an integral part of game progression, and it may take a few minutes or even days, depending on your luck. It saves you time by skipping the tedious steps. With Rerolling feature, you can perform multiple summonses simultaneously and speed up the process to unlock powerful heroes. So that everyone can play games across language barriers. With Real-time Translation, you can translate your favorite Android games on your PC in your desired language. Farm mode keeps your PC up and running when multiple instances are at work. Now you can create more, and do more with less PC Usage. ![]() When running multiple BlueStacks instances, Eco Mode minimizes your PC’s resources. With this feature, you can sync the action of the primary instance on all other instances in real time & replicate the same action without any extra effort. With Multi-instance, playing multiple Android games on your PC simultaneously becomes easy simply by creating several instances of BlueStack. You can move your character much faster on a map by using the mouse Multi-instance This gives you a chance to become the ultimate warrior with a much more dynamic and controlled gaming experience than your mobile phone. With the advanced features of BlueStack, you can play MOBA games with special control Schemes Like a Pro. You can act faster than your enemy more kills mean more victories. Using the keyboard and mouse to look around the shoot, move the character. Once enabled, it gives you the power to bask in the glory of thrilling headshots. To activate the shooting mode ‘Press F1 to Aim & Shoot with the mouse’. In this game, the scenario is ‘shooting mode on- game on’. This gives you an incredibly empowering experience.Īdditionally, you are able to customize game controlsīlueStack permits you to rule the battlefield in your favorite Android Games- Free Fire, PUBG Mobile, and COD Mobile. You’re allowed to share your controls with your gaming buddies by export and import controls. The ease that a keyboard and mouse offer has no match with tricky touch control. Now you can control and play your games on PC, just the way you want, either with a gamepad or keyboard mouse. List some of the features below Game Controls With its Key Mapping features, you can control your game in a more straightforward, faster way with a keyboard and mouse. It also allows you to run all kinds of Google Play Apps and apps from anywhere else. When it comes to compatibility features, BlueStacks App Player is capable of running tons of apps. It has several sparkling features, including game control, shooting mode, Multi-instance, and more. FeaturesīlueStacks is a brilliant app that provides you with the best gaming experience. Your game will never interrupt by calls or text messages. These features change the way you play mobile games. BlueStacks gives better performance, a bigger screen, and more accurate controls to provide the best gaming experience to its users. ![]() You can download using a native app store linked to Bluestacks, accessing Google Play from your browser, or downloading APK files. Moreover, you’ll have several different options to download apps. You can still download apps and use them the same as above. If you don’t have one, that’s not a big issue. If you do, that’s great, it will allow you to sync all of your apps and tasks from your account. When running the program, it will ask you if you have an Android phone. With BlueStacks, you can play 1M+ Android Games. Its interface will allow you to manage all the features on your virtual device, with permission to download and install tons of different apps in just a few seconds. So, if you want an easy, comfortable menu, BlueStacks will be the best app for you. BlueStacks App Player is a tool that permits you to run Android applications on your PC. ![]() ![]() ![]() It has a sweet and creamy taste with a hint of fresh strawberries, making it the perfect drink to enjoy on a warm summer day. Starting with the newest flavor, Baileys Strawberry and Cream is an excellent addition to the brand's lineup. In this article, we will take a closer look at the different flavors of Baileys and what makes each one stand out. However, over the years, Baileys has introduced several new flavors, each with its own unique taste and appeal. It is made with Irish whiskey, cream, and cocoa, and has a unique taste that sets it apart from othr liqueurs on the market. To continue your exploration, here is a list of liqueur prices in Kenya.Baileys is a popular liqueur that has been enjoyed by many for decades. Dial us now to order this drink or other alcohol delivery services. It is your turn to experience gloriousness attributed to this liqueur. Whichever you choose, we will deliver it to you in the least time possible at your most convenient venue. You can choose to order the 1 litre or 750 ml bottle. This liqueur is available in our liquor store at the most affordable price in Nairobi. It is your turn now to experience the exuberance contained in this Irish drink. Baileys have won the hearts of many across the world. The luxury that accompanies this liqueur is unmatched when compared to other cream liqueurs. Its appearance is a complement to its taste. This makes it a presentable gift to your chocolate, cream, or vanilla loving girlfriend. Baileys cream also brings out the best in cocktails by providing warmth and style perfect for any occasion.īaileys is available in a beautiful, professionally crafted, unique bottle and easily identifiable. There is no limitation on how to enjoy this whiskey-based Irish cream. The taste in this liqueur gives you an option to explore. This should be fun! You can also find out on your own how you can best enjoy this liqueur by experimenting with various delicacies until you find your perfect combination. There is more to how you can best enjoy this liqueur – try it with pie, cheesecake, or muffins. Baileys Irish Cream has its own unique taste that stimulates your taste buds, and if you are seeking to experience the flavors and aromas, then taking it neat will create the exuberance you have been yearning for so long. To best enjoy this liqueur, you may choose to swirl it in your favorite coffee, drizzle it over vanilla ice cream to experience an indulgent treat, pour it over ice, and other baileys cocktails, or take it neat to have a full experience of the flavors and aromas. Baileys liqueur creates an indulging warm sensation from its velvety texture, a welcoming alcohol content, emancipating you from boredom and fatigue from a busy day you had at work. ![]() This is a drink that will rock your house party or that dinner date you have been yearning for. There you go, mate! Your pursuit for a luxurious, smooth, and best-tasting liqueur ends at Baileys Irish Cream. It remains to be the world’s most celebrated liqueur. The combination of cream and triple distilled whiskey is all a result of talent and skill, which led to Baileys Irish Cream to win awards every year since 2003. Its production and bottling are exclusively done in Ireland, a land full of perfection in distilling and dairy production and processing. ![]() On the palate, the liqueur provides a lingering silky smooth, creamy finish. The soft aromas of chocolate and vanilla add to its unique complexity with a taste of quality. The alluring taste is complemented by rich cream, vanilla, and cocoa notes. This is a unique type of liquor, a blend of Irish whiskey and dairy cream classified as a liqueur, with a characteristic cream composition that makes it one of the liqueurs in the whole world. Since 1974, Baileys, a product of Diageo, has been the world’s best-selling Irish cream liqueur. ![]() ![]() Post memes/jokes in /r/chemistrymemes and /r/chemistryjokes. Any such posts will be deleted.Īsk education and jobs questions in the current weekly topic. Oh and of course if you got a more complex system than one atom you want to not only define the distance of that dummy atom but also the angles, so it's. If you're looking for a more concentrated, advanced discussion of chemistry topics among professionals and grad students, check out /r/Chempros.īefore asking "What chemical is this?" see this chart. You can substitute the 'Na' line with your cartesian coordinates, but then the numbering in the z-matrix section changes you have to adopt those numbers. Click here for the OSHA chemical data site and here for a multicompany MSDS aggregate search. Here you can format and select z-matrix for Gaussian input. Using the above Z-matrix, the full C3v symmetry of ammonia is recognized by Gaussian, but optimization is consequently performed in the Cs point group due. Just draw the molecule, then navigate to menu Extensions Gaussian. Solution 2 Avogadro, nice, clean and very user friendly. Gelessus, Impressum, Datenschutzerklrung. Solution 1 Try Open Babel, the windows GUI has a lot of features that may be of help depending on what are those specifics you need in your Z-matrix. If you spill/injure yourself contact medical professionals and read the MSDS, do not post to this reddit. Gelessus, Impressum, Datenschutzerklrung/DataPrivacyStatement th 2022 by A. Yes links to blogs, images, videos, comics, and infographics are okay especially if they are on your personal website. The Z-matrix in Computational Chemistry 5381 2019 L07 Physical Chemistry (PCHEM) at Sam 2.69K subscribers Subscribe 3.6K views 3 years ago 2019 5381 Lectures - Thermodynamics Defining the molecular. No physorg, sciencedaily, or other press release aggregator spam! Since I use CFOUR (not GAUSSIAN), I know of this page that might help with learning about dummy atoms for Z-matrices (search for 'dummy'):. If a caption or explanation is included this helps, but please use your discretion.īefore asking about chemical drawing/illustration programs, look at your school's IT/software website and see if they provide an institutional license of ChemDraw (hint: if they have a chemistry department, they will) \begingroup QuantumX Okay, then if you're using ZMAT, there's always strange oddities that require dummy atoms (this is not just in Gaussian, but also in CFOUR, for example). Likewise, simple pictures of uninteresting and garden variety chemistry-related things are not appreciated. No memes, rage comics, image macros, reaction gifs, or other "zero-content" material. However, academic discussions on pharmaceutical chemistry and the science of explosives are permitted. Rules: Violating a rule will result in a ban.Īsk homework, exam, lab, and other undergraduate-level questions at ChemicalForums otherwise it will be deleted.ĭiscussions on illicit drug synthesis, bomb making, and other illegal activities are not allowed and will lead to a ban. ![]() ![]() ![]() ![]()
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